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Milledgeville is a village in Fayette County, Ohio, United States. The population was 112 at the 2010 census.
Milledgeville was laid out in 1855. A mill was built on the town site in 1855. The name Milledgeville is an amalgamation of "mill on the edge of ville". A post office has been in operation at Milledgeville since 1877.
Milledgeville is located at 39°35′35″N 83°35′15″W (39.593121, -83.587608).
According to the United States Census Bureau, the village has a total area of 0.10 square miles (0.26 km2), all land.
As of the census of 2010, there were 112 people, 50 households, and 29 families residing in the village. The population density was 1,120.0 inhabitants per square mile (432.4/km2). There were 55 housing units at an average density of 550.0 per square mile (212.4/km2). The racial makeup of the village was 95.5% White, 1.8% African American, 0.9% Asian, 0.9% from other races, and 0.9% from two or more races.
There were 50 households of which 26.0% had children under the age of 18 living with them, 34.0% were married couples living together, 16.0% had a female householder with no husband present, 8.0% had a male householder with no wife present, and 42.0% were non-families.